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Journal of Dairy Science Vol. 45 No. 3 311-316
© 1962 by American Dairy Science Association ®
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Relation of Linoleate and Linolenate to the Flavors of Autoxidized Milk Fat1

A. M. El-Negoumy, M. S. de Puchal and E. G. Hammond

Department of Dairy and Food Industry, Iowa State University of Science and Technology, Ames

ABSTRACT

Flavor concentrates obtained by high-vacuum distillation of the fat from autoxidized butter were fractionated by gas chromatography on butanediol succinate. The tallowy flavor of the concentrate was reproduced by recombining three of the 12 gas chromatograph fractions. The first of these components migrated close to octanal on the gas chromatograph and gave an oxidized flavor to milk. The second component migrated close to undecanal and gave a grassy flavor to milk. The third component was 2,4-decadienal, which gave milk an oily flavor. The component which gave an oxidized flavor in homogenized milk at low concentration gave a metallic flavor in the fat phase at higher concentrations. Methyl linoleate was a precursor for the oxidized and oily flavors, and methyl linolenate was a precursor of the grassy flavor. These compounds are probably responsible for the major flavor characteristics of other autoxidized fats and oils.


FOOTNOTES

1 Journal Paper No. J-4155 of the Iowa Agricultural and Home Economics Experiment Station, Ames, Iowa. Project No. 1128. A report of work done under contract with the U. S. Department of Agriculture and authorized by the Research and Marketing Act of 1946. The contract is being supervised by the Eastern Utilization Research and Development Division of the Agricultural Research Service.







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Copyright © 1962 by the American Dairy Science Association ®.